Reactions of organic anions. CLXII. Why do η6-arenetricarbonylchromium(0) ?-comlexes not enter the vicarious nucleophilic substitution of hydrogen?

DOI: 10.1016/0022-328X(89)87210-9

Source and publish data:

Journal of Organometallic Chemistry p. 95 - 100 (1989)

Update date:2022-07-30

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Authors:

Ostrowski, Stanislaw

Makosza, Mieczyslaw

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Article abstract of DOI:10.1016/0022-328X(89)87210-9

Attempts to perform the vicarious nucleophilic substitution of hydrogen in highly electrophilic η⁶-arenetricarbonylchromium(0) ?-complexes failed.Reasons for this unexpected failure are discussed.

Full text of DOI:10.1016/0022-328X(89)87210-9

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