Journal of the Chemical Society. Chemical communications p. 1495 - 1496 (1989)
Update date:2022-08-04
Topics:
Jentsch, Dieter
Jones, Peter G.
Thoene, Carsten
Schwarzmann, Einhard
The reaction of CS2 with gold(III) chloride (Au2Cl6) leads to the complex AuCl2(η2-S2CCl), in which the CS2 has inserted into an Au-Cl bond of a hypothetical monomeric gold(III) trichloride intermediate; the structure has been confirmed by ray crystallography, although the S and Cl atoms could not be distinguished.
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