Gas-phase reactivity of sulphur ions with ammonia

Article abstract of DOI:10.1063/1.465499

The gas-phase reactions of sulphur cluster ions, cations Sn⁺ (n = 1,...,8) and anions Sn^- (n = 2,...,6) with NH3 have been studied by means of a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer.Relative and absolute reaction rate constants as well as reaction efficiencies have been determined.The S4⁺ cation has by the far highest reactivity with all other sulphur cations being significantly less reactive.Besides some fragmentation, no reactivity of the anions was found.Structural conclusions are made based on the present experiments, on previous extensive ab initio calculations, and on complementary experiments.

Full text of DOI:10.1063/1.465499

Gasphase reactivity of sulphur ions with ammonia
Gereon NiednerSchatteburg, Thomas Schindler, Christian Berg, Dirk Wössner, and Vladimir E. Bondybey
Citation: The Journal of Chemical Physics 99, 9664 (1993); doi: 10.1063/1.465499
View online: http://dx.doi.org/10.1063/1.465499
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/99/12?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
130.113.86.233 On: Mon, 15 Dec 2014 19:55:31