Preparation and Characterisation of , , BF4, and BF4

DOI: 10.1039/DT9900000925

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 925 - 930 (1990)

Update date:2022-08-03

Topics:

Authors:

Parkin, Ivan P.

Woolins, J. Derek

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9900000925

Reaction of 2Cl2, or SeCl4-Cl, with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia gives complexes of the type (ca. 70percent yield).Reaction of SeCl4 with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia produces in variable yield (ca. 24-74percent).Treatment of or with HBF4 in tetrahydrofuran-benzene produces BF4 or BF4 quantitatively according to 31P n.m.r., i.r., mass spectra, and microanalyses.Proton-exchange reactions reveal increasing basicity in the series ca. , , .

Full text of DOI:10.1039/DT9900000925

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Pt(Se₂N₂)(PCH₃(C₆H₅)2)2}

Cas No:125984-22-7

R&D Labs maybe for 125984-22-7

Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Shanghai Hanshare Industry Co.,Ltd.

Contact:86 21 20960688

Address:RM902-903,Building E, Wanda Plaza,No.26,Zhoukang Road, Pudong District, Shanghai, China
YingYing Pharmaceutical Co.,Ltd

Contact:86-18854126208

Address:55#, yingxiongshan road
SPE Chemicals Co.,Ltd

Contact:

Address:ROOM 1715, No#345 Jin Xiang Road, Pudong District

Relevant to this article

Aluminum hydrogen sulfate as a green catalyst for the solvent-free synthesis of pyrazolopyridines

Doi:10.1134/S1070363215050308
(2015)
Double hydrophosphorylation of nitriles catalyzed by rare-earth-metal lanthanum

Doi:10.1021/acs.joc.0c02016
(2020)
Synthesis, structure, and properties of dicarbonyl bis(phosphine) 1,4-diphenyltetraazabutadiene complexes of molybdenum and tungsten

Doi:10.1021/om00119a018
(1990)
Facile assembly of 1-(4-haloisoquinolin-1-yl)ureas via a reaction of 2-alkynylbenzaldoxime, carbodiimide, and halide in water

Doi:10.1016/j.tet.2014.02.026
(2014)
Concise total synthesis of

Doi:10.1021/ol802425m
(2009)
Doi:10.1021/jm00321a016
(1966)

Article Doi