Preparation and Characterisation of , , BF4, and BF4

DOI: 10.1039/DT9900000925

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 925 - 930 (1990)

Update date:2022-08-03

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Authors:

Parkin, Ivan P.

Woolins, J. Derek

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Article abstract of DOI:10.1039/DT9900000925

Reaction of 2Cl2, or SeCl4-Cl, with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia gives complexes of the type (ca. 70percent yield).Reaction of SeCl4 with (PR3 = PEt3, PMe2Ph, PMePh2, PPh3, or 1/2 Ph2PCH2CH2PPh2) in liquid ammonia produces in variable yield (ca. 24-74percent).Treatment of or with HBF4 in tetrahydrofuran-benzene produces BF4 or BF4 quantitatively according to 31P n.m.r., i.r., mass spectra, and microanalyses.Proton-exchange reactions reveal increasing basicity in the series ca. , , .

Full text of DOI:10.1039/DT9900000925

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