Diastereoisomer separation and absolute configuration of (ortho- and (meta-MeC6H4CO2Me)Cr(CO)2L (L=(+)-neomenthyl-PPh2)

DOI: 10.1016/0022-328X(89)87274-2

Source and publish data:

Journal of Organometallic Chemistry p. 51 - 64 (1989)

Update date:2022-07-29

Topics:

Authors:

Jaouen, Gerard

Howell, James A. S.

Tirvengadum, Marie-Claire

McArdle, Patrick

Cunningham, Desmond

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Article abstract of DOI:10.1016/0022-328X(89)87274-2

Replacement of a carbonyl ligand by (+)-neomenthylPPh2 provides a method for diastereoisomer separation of the methyl esters of (ortho- and (para-toluic acid)Cr(CO)3.The absolute planar configurations have been assigned.

Full text of DOI:10.1016/0022-328X(89)87274-2

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