PREPARATION OF α-FLUORO-α,β-UNSATURATED ESTERS VIA TWO CARBON HOMOLOGATION OF ESTERS

DOI: 10.1016/S0040-4039(01)93802-X

Source and publish data:

Tetrahedron Letters p. 5571 - 5574 (1989)

Update date:2022-08-04

Topics:

Authors:

Thenappan, Alagappan

Burton, Donald J.

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Article abstract of DOI:10.1016/S0040-4039(01)93802-X

In the presence of diisobutyl aluminium hydride, esters react with an anion derived from (EtO)2P(O)CFHC(O)OEt to give the title compounds in good yields.The scope of this method and the factors which influence the stereochemistry of the products are discussed.

Full text of DOI:10.1016/S0040-4039(01)93802-X

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