A 4-Dimethylaminopyridine-Catalyzed Aminolysis of β-Ketoesters. Formation of β-Ketoamides

DOI: 10.1055/s-1989-27383

Source and publish data:

Synthesis p. 753 - 755 (1989)

Update date:2022-08-05

Topics:

Authors:

Cossy, Janine

Thellend, Annie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1989-27383

Alkyl 3-oxoalkanoates (β-ketoesters) react with amines in the presence of a catalytic amount of 4-dimethylaminopyridine (DMAP) under mild conditions to form 3-oxoalkanamides (β-ketoamides) in good yields.

Full text of DOI:10.1055/s-1989-27383

Products guided by the article

Product name:2-Oxo-cyclohexanecarboxylic acid dipropylamide

Cas No:126486-34-8

R&D Labs maybe for 126486-34-8

Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
Chongqing KonAo Health Co.,Ltd

Contact:13687578375

Address:wuhan hubei china
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China
JIANGXI XINXIN CHEMICAL CO., LTD.

Contact:86-15957176628

Address:INDUSTRY ROAD 1, INDUSTRIAL PARK, HEKOU TOWN,YANSHAN COUNTY, JIANGXI PROVINCE, CHINA
LianYunGang Chiral Chemical(CHINA) CO.,LTD

Contact:+86-518-83616958 +86-519-82884848

Address:LianYunGang Chemical Industry Park (JiangSu)

Relevant to this article

CYCLOADDITION OF β-SUBSTITUTED ENONES TO A BICYCLICSYDNONE: OBSERVATION OF AN UNEXPECTED FACILE HYDROCARBON ELIMINATION

Doi:10.1016/S0040-4039(01)80759-0
(1989)
Convenient synthesis of tridentate 2,6-di(pyrazol-1-yl)-4-carboxypyridine and tetradentate 6,6′-di(pyrazol-1-yl)-4,4′-dicarboxy-2,2′- bipyridine ligands

Doi:10.1016/j.tetlet.2010.12.001
(2011)
Building addressable libraries: Site-selective use of Pd(0) catalysts on microelectrode arrays

Doi:10.1021/ja107490t
(2010)
4-(1,9a-Dihydro-2H-quinolizin-2-ylidene)morpholinium Salts from 4-(1-Methyl-3-phenyl-3-trifluoromethylsulfonyloxy-2-propenylidene)morpholinium Trifluoromethanesulfonate

Doi:10.1055/s-1989-27376
(1989)
Adamantylazoles: XIV.¹ acid-catalyzed alkylation of 5-aminotetrazoles with tertiary alcohols

Doi:10.1134/S1070363210110228
(2010)
Syntheses and crystal structures of two azide-bridged dinuclear zinc(II) complexes with Schiff bases and halides

Doi:10.1080/15533174.2011.609503
(2012)

Article Doi