A 4-Dimethylaminopyridine-Catalyzed Aminolysis of β-Ketoesters. Formation of β-Ketoamides

DOI: 10.1055/s-1989-27383

Source and publish data:

Synthesis p. 753 - 755 (1989)

Update date:2022-08-05

Topics:

Authors:

Cossy, Janine

Thellend, Annie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1989-27383

Alkyl 3-oxoalkanoates (β-ketoesters) react with amines in the presence of a catalytic amount of 4-dimethylaminopyridine (DMAP) under mild conditions to form 3-oxoalkanamides (β-ketoamides) in good yields.

Full text of DOI:10.1055/s-1989-27383

Products guided by the article

Product name:2-Oxo-cyclohexanecarboxylic acid dipropylamide

Cas No:126486-34-8

R&D Labs maybe for 126486-34-8

SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Lyrin Industrial Corporation Limited

Contact:86-731-82571800

Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
Huaihua Baohua Biotechnology Co.,Ltd

website:http://www.baochengchem.com

Contact:86-519-82698291

Address:HouYang chemical development zone,Jintan,Jiangsu,China (213200)
Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China

Relevant to this article

CYCLOADDITION OF β-SUBSTITUTED ENONES TO A BICYCLICSYDNONE: OBSERVATION OF AN UNEXPECTED FACILE HYDROCARBON ELIMINATION

Doi:10.1016/S0040-4039(01)80759-0
(1989)
Convenient synthesis of tridentate 2,6-di(pyrazol-1-yl)-4-carboxypyridine and tetradentate 6,6′-di(pyrazol-1-yl)-4,4′-dicarboxy-2,2′- bipyridine ligands

Doi:10.1016/j.tetlet.2010.12.001
(2011)
Building addressable libraries: Site-selective use of Pd(0) catalysts on microelectrode arrays

Doi:10.1021/ja107490t
(2010)
4-(1,9a-Dihydro-2H-quinolizin-2-ylidene)morpholinium Salts from 4-(1-Methyl-3-phenyl-3-trifluoromethylsulfonyloxy-2-propenylidene)morpholinium Trifluoromethanesulfonate

Doi:10.1055/s-1989-27376
(1989)
Adamantylazoles: XIV.¹ acid-catalyzed alkylation of 5-aminotetrazoles with tertiary alcohols

Doi:10.1134/S1070363210110228
(2010)
Syntheses and crystal structures of two azide-bridged dinuclear zinc(II) complexes with Schiff bases and halides

Doi:10.1080/15533174.2011.609503
(2012)

Article Doi