A 4-Dimethylaminopyridine-Catalyzed Aminolysis of β-Ketoesters. Formation of β-Ketoamides

DOI: 10.1055/s-1989-27383

Source and publish data:

Synthesis p. 753 - 755 (1989)

Update date:2022-08-05

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Authors:

Cossy, Janine

Thellend, Annie

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Article abstract of DOI:10.1055/s-1989-27383

Alkyl 3-oxoalkanoates (β-ketoesters) react with amines in the presence of a catalytic amount of 4-dimethylaminopyridine (DMAP) under mild conditions to form 3-oxoalkanamides (β-ketoamides) in good yields.

Full text of DOI:10.1055/s-1989-27383

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