CHEMICALLY INITIATED ELECTRON-EXCHANGE LUMINESCENCE OF Ru(bpy)3Cl2 IN CATALYTIC REACTION WITH 1,2-DIOXETANE

DOI: 10.1007/BF00961288

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1158 - 1162 (1991)

Update date:2022-07-30

Topics:

Authors:

Voloshin, A. I.

Sharipov, G. L.

Kazakov, V. P.

Tolstikov, G. A.

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Article abstract of DOI:10.1007/BF00961288

We have investigated chemiluminescence activated by Ru(bpy)3Cl2 in the reaction of decomposition of 1,2-dioxetane.Catalysis and activation of chemiluminescence of 1.2-dioxetanes by a ruthenium complex occur according to a mechanism of chemically initiated electron exchange, which leads to effective excitation of Ru(bpy)3Cl2 with yield φ^*_Ru = 0.20 +/- 0.05.

Full text of DOI:10.1007/BF00961288

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