Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1158 - 1162 (1991)
Update date:2022-07-30
Topics:
Voloshin, A. I.
Sharipov, G. L.
Kazakov, V. P.
Tolstikov, G. A.
We have investigated chemiluminescence activated by Ru(bpy)3Cl2 in the reaction of decomposition of 1,2-dioxetane.Catalysis and activation of chemiluminescence of 1.2-dioxetanes by a ruthenium complex occur according to a mechanism of chemically initiated electron exchange, which leads to effective excitation of Ru(bpy)3Cl2 with yield φ*Ru = 0.20 +/- 0.05.
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