Tetrahedron Letters p. 5105 - 5108 (1989)
Update date:2022-08-05
Topics:
Rousset, Christophe J.
Swanson, Douglas R.
Lamaty, Frederic
Negishi, Ei-ichi
The Zr-promoted bicyclization of 1,6- and 1,7-dienes can stereoselectively produce trans-zirconabicyclo<3.3.0>octanes and cis-zirconabicyclo<4.3.0>nonanes, respectively; these compounds can be readily converted into protonolysis, halogenolysis, and carbonylation products.
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