The First Internally Functionalized Chiral Metacyclophanes

DOI: 10.1039/C39890001757

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1757 - 1759 (1989)

Update date:2022-08-04

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Authors:

Voegtle, Fritz

Ostrowicki, Andreas

Knops, Peter

Fischer, Peter

Reuter, Hans

Jansen, Martin

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Article abstract of DOI:10.1039/C39890001757

The new medium membered heterocycles (2c-i), additionally strained due to internal substituents, could be obtained after optimization of a simple one-step cyclisation reaction; the barrier of the restricted rotations of the phenyl ring in (2h) and of the

Full text of DOI:10.1039/C39890001757

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Product name:8-Methoxy-N-(p-tolylsulfonyl)-1-thia-10-aza<2.2>metacyclophan

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