Enantioselective cycloadditions of 2-alkenoylpyridine-N-oxides catalysed by a bis(oxazoline)/CuII complex: Structure of the reactive intermediate

DOI: 10.1002/chem.201002017

Source and publish data:

Chemistry - A European Journal p. 516 - 520 (2011)

Update date:2022-07-31

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Authors:

Livieri, Alessandro

Boiocchi, Massimo

Desimoni, Giovanni

Faita, Giuseppe

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Article abstract of DOI:10.1002/chem.201002017

Diels-Alder and 1,3-dipolar cycloadditions involving (E)-3-aryl-1-(pyridin- 2-yl-N-oxide)prop-2-en-1-ones as the 2π components are efficiently catalysed by bis(oxazoline)-Cu^II complexes. The cycloadducts are obtained in quantitative yields with

Full text of DOI:10.1002/chem.201002017

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Product name:(-)-(1S,2R,3R,4R)-2-[3-(4-bromophenyl)bicyclo[2.2.1]hept-5-enecarbonyl]pyridine-1-oxide

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