Angewandte Chemie - International Edition p. 1109 - 1113 (2011)
Update date:2022-07-31
Topics: Cross-coupling C-H Activation Experimental procedure Grignard reagents Cobalt catalysis
Li, Bin
Wu, Zhen-Hua
Gu, Yi-Fan
Sun, Chang-Liang
Wang, Bai-Quan
Shi, Zhang-Jie
Go go Grignard! The first highly regioselective, cobalt-catalyzed C-H transformation of benzo[h]quinoline and phenylpyridine derivatives with Grignard reagents at room temperature has been achieved (see scheme). Both aryl and alkyl Grignard reagents showed significant reactivity.
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