Alkyl(phenylthio)ketenes as Synthetic Equivalents of Monoalylketenes: A Concise General Route To 3-Alkyl β-Lactams as Carbapenem Building-Blocks

DOI: 10.1016/S0040-4039(01)80749-8

Source and publish data:

Tetrahedron Letters p. 4577 - 4580 (1989)

Update date:2022-08-04

Topics:

Authors:

Palomo, Claudio

Cossio, Fernando P.

Odriozola, Jose M.

Oiarbide, Mikel

Ontoria, Jesus M.

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Article abstract of DOI:10.1016/S0040-4039(01)80749-8

The dehydrochlorination of α-phenylthioalkanoyl chlorides with triethylamine in presence of imines produced a high yield formation of α-phenylthio β-lactams which upon desulfuration furnished a wide variety of 3-alkyl β-lactams in a high stereoselective f

Full text of DOI:10.1016/S0040-4039(01)80749-8

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