Ruthenium-Catalyzed Chlorine Atom Transfer Cyclizations of N-Allylic α-Chloro-α-thioacetamides. Synthesis of (-)-Trachelanthamidine and Formal Total Synthesis of (+/-)-Haemanthidine and (+/-)-Pretazettine

DOI: 10.1021/jo00061a005

Source and publish data:

Journal of Organic Chemistry p. 2360 - 2368 (1993)

Update date:2022-08-03

Topics:

Authors:

Ishibashi, Hiroyuki

Uemura, Nahoko

Nakatani, Hiroshi

Okazaki, Mika

Sato, Tatsunori

et al. et al.

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Article abstract of DOI:10.1021/jo00061a005

A new method for the synthesis of five-membered lactams by ruthenium-catalyzed chlorine atom transfer cyclizations of N-allylic α-chloro-α-thioacetamides and the application of the method to the synthesis of the title alkaloids are described.A benzene sol

Full text of DOI:10.1021/jo00061a005

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