A FORMAL STEREOCONTROLLED SYNTHESIS OF (+/-) ISOCLOVENE

DOI: 10.1016/S0040-4020(01)89151-1

Source and publish data:

Tetrahedron p. 6833 - 6840 (1989)

Update date:2022-08-03

Topics: Chiral Auxiliary Reaction Optimization Experimental Design Stereocontrolled Formal Synthesis

Authors:

Ahmad, Zafeer

Goswami, Pannalal

Venkateswaran, R. V.

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Article abstract of DOI:10.1016/S0040-4020(01)89151-1

Starting from a seven-membered ring compound, the synthesis of the tricyclic ketone (25) is described concluding a formal total synthesis of (+/-) isoclovene, the major sesquiterpene from extensive rearrangement of caryophyllene.Enroute, a facile base pro

Full text of DOI:10.1016/S0040-4020(01)89151-1

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