Dithiocarboxylation of α-Nitrogen-Carbanions

DOI: 10.1007/BF00811126

Source and publish data:

Monatshefte fur Chemie p. 871 - 878 (1989)

Update date:2022-07-29

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Authors:

Kindt, Petra

Doelling, Wolfgang

Augustin, Manfred

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Article abstract of DOI:10.1007/BF00811126

Dithiocarbamic acid esters 1 with CH-acidic methylene group adjacent to nitrogen react in the system dimethylformamide + 2 equivalents sodium tert. butoxide with carbon disulphide yielding 1,3-thiazoline-2-thiones 3. 2,5-Bis(alkylthio)-1,3-thiazoles 6 are available via dithiocarboxylation of isothiocyanate 5. - Keywords: Dithiocarbamic acid esters; 1,3-Thiazoline-2-thiones; 2-Alkylthio-1,3-thiazoles; 1,3-Thiazole-derivatives.

Full text of DOI:10.1007/BF00811126

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