Journal of Organic Chemistry p. 3723 - 3727 (1990)
Update date:2022-07-29
Topics:
Williams
Hendrix
The asymmetric synthesis of several arylglycines are reported. The methodology deployed involves either cuprate or Friedel - Crafts couplings to chiral bromoglycinates. The % ee's range from 82 to 94%. Both an oxidative and reductive protocol are employed to unmask the oxazinone chiral auxilliary providing the free α-amino acids.
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