CHIRALITY TRANSFER IN THE 1,5-HYDRIDE SHIFT OF A STANNYL COMPOUND HAVING CATIONIC CENTER AT δ-POSITION

DOI: 10.1016/S0040-4039(01)80560-8

Source and publish data:

Tetrahedron Letters p. 4983 - 4984 (1989)

Update date:2022-07-29

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Authors:

Sato, Tadashi

Haramura, Masayuki

Taka, Naoki

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Article abstract of DOI:10.1016/S0040-4039(01)80560-8

Chirality transfer with 7:1 selectivity was realized in the I2/AgOTf-induced 1,5-hydride shift of 2-methyl-5(R)-trimethylstannyl-1-hexene to 6-iodo-5(S)-methyl-1-hexene.

Full text of DOI:10.1016/S0040-4039(01)80560-8

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