
Journal of the American Chemical Society p. 4942 - 4945 (1990)
Update date:2022-08-03
Topics:
Guo, Zhi-Wei
Wu, Shih-Hsiung
Chen, Ching-Shih
Girdaukas, Gary
Sih, Charles J.
Quantitative expressions that govern sequential kinetic resolutions have been developed for calculation of the relative kinetic constants to allow optimization of chemical and optical yields. Enantiomerically pure (2R,4R)-and (2S,4S)-2,4-pentanediols have been prepared by biocatalyzed sequential enantioselective esterification in anhydrous isooctane.
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