Chemistry of Heterocyclic Compounds p. 146 - 148 (1990)
Update date:2022-08-15
Topics:
Kazaryan, P. I.
Avakyan, S. V.
Simonyan, E. S.
Gevorkyan, A. A.
1-R-3-Methyl-2,3-epoxybutanes have been found to react with trifluoroacetic anhydride at 20-40 deg C in the absence of a catalyst to give mixtures of the ditrifluoroacetate and the product of substitutive O-acylation.The formation of the latter is favored by raising the temperature.The reaction mechanism is discussed.
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