Reactions of N-alkoxycarbonyl alkyldiphenyl-λ5-phosphazenes with acetylene esters. Synthesis of 1-aza-2-oxo-4λ5-phosphinines

DOI: 10.1016/0022-328X(90)85215-K

Source and publish data:

Journal of Organometallic Chemistry p. 61 - 67 (1990)

Update date:2022-07-30

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Authors:

Barluenga, Jose

Lopez, Fernando

Palacios, Francisco

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Article abstract of DOI:10.1016/0022-328X(90)85215-K

N-Alkoxycarbonyl alkyldiphenyl-λ⁵-phosphazenes react with acetylene esters yielding stabilized phosphonium ylides.Subsequent metalation with KH leads to azaphosphinines.

Full text of DOI:10.1016/0022-328X(90)85215-K

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