Tetrahedron Letters p. 6781 - 6784 (1989)
Update date:2022-08-04
Topics:
Bailey
Wilson
Brown
Pipecolic acid derivatives can be prepared by the aza-Diels-Alder reaction of dienes with the iminium salt derived from benzylamine and ethyl glyoxylate in DMF; the presence of a catalytic quantity of water is essential, and acyclic dienes react with high regio- and diastereoselectivity.
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