Stereoselective synthesis of pipecolic acid derivatives using a aza-Diels-Alder reactions

DOI: 10.1016/S0040-4039(00)70675-7

Source and publish data:

Tetrahedron Letters p. 6781 - 6784 (1989)

Update date:2022-08-04

Topics:

Authors:

Bailey Bailey

Wilson Wilson

Brown Brown

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)70675-7

Pipecolic acid derivatives can be prepared by the aza-Diels-Alder reaction of dienes with the iminium salt derived from benzylamine and ethyl glyoxylate in DMF; the presence of a catalytic quantity of water is essential, and acyclic dienes react with high regio- and diastereoselectivity.

Full text of DOI:10.1016/S0040-4039(00)70675-7

Products guided by the article

Product name:endo-2-aza-2-benzyl-3-ethoxycarbonyl<2.2.2>bicyclooct-5-ene

Cas No:127897-23-8

R&D Labs maybe for 127897-23-8

Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
Sinoway International (Jiangsu) Co., Ltd.

Contact:+86-25-86630167

Address:17 Beijing Road (West), Nanjing, China
Lanling Hongchuang Flame Retardant Co., Ltd.

Contact:+86-531-68858132

Address:East Huafeichang Road, Cangshan County, Linyi, Shandong, China (Mainland)
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Henan Sinotech Import&Export Corporation

website:http://www.hasinotech.com

Contact:86-371-86181678

Address:No. 260, Dongming Road,Jinshui District

Relevant to this article

Evaluation of 1,2,5-thiadiazoles as modulators of M₁/M ₅ muscarinic receptor subtypes

Doi:10.1016/j.bmc.2014.01.049
(2014)
Salicylanilide diethyl phosphates as cholinesterases inhibitors

Doi:10.1016/j.bioorg.2014.11.005
(2015)
Enantioselective formal α-allylation of nitroalkanes through a chiral iminophosphorane-catalyzed Michael reaction-Julia-Kocienski olefination sequence

Doi:10.1039/c3cc49477b
(2014)
A smart approach to achieve an exceptionally high loading of metal nanoparticles supported by functionalized extended frameworks for efficient catalysis

Doi:10.1039/c4cc09228g
(2015)
Synthesis, growth, crystal structure, spectral, thermal, mechanical and optical studies of stilbazolium derivative single crystal: 2-[2-(4-Diethylamino- phenyl)-vinyl]-1-methyl-pyridinium naphthalene-2-sulfonate (DESNS)

Doi:10.1016/j.saa.2014.01.064
(2014)
Synthesis of naphthalene amino esters by the blaise reaction of o -alkynylarenenitriles

Doi:10.1021/jo500137m
(2014)

Article Doi