Cyclometallated compounds IV. Cyclopalladation of phenylpyrimidines and X-ray structure of a doubly cyclopalladated derivative of 4,6-diphenylpyrimidine

DOI: 10.1016/0022-328X(90)80223-M

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Journal of Organometallic Chemistry p. 455 - 469 (1990)

Update date:2022-08-05

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Authors:

Caygill, Graham B.

Hartshorn, Richard M.

Steel, Peter J.

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Article abstract of DOI:10.1016/0022-328X(90)80223-M

Seven phenylpyrimidines have been cyclopalladated with lithium tetrachloropalladate and the products characterized by 1H and 13C NMR studies of their acetylacetonate complexes. 6-Methyl-2,4-diphenylpyrimidine and 2,4,6-triphenylpyrimidine undergo preferen

Full text of DOI:10.1016/0022-328X(90)80223-M

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