Tetrahedron Letters p. 5933 - 5936 (1989)
Update date:2022-07-30
Topics: Experimental terms
Villa, Maria-Jesus
Warren, Stuart
The title compounds (1) undergo a <1,4>-PhS shift to give an E,Z mixture of vinyl sulphides (2) with thionyl chloride but only the Z isomer if toluene-p-sulphonic acid is used.The reaction occurs only if another PhS group is present β to the hydroxyl.The
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