Tetrahedron Letters p. 139 - 142 (1990)
Update date:2022-09-26
Topics:
Pellicciari, Roberto
Natalini, Benedetto
Marinozzi, Maura
Monahan, Joseph B.
Snyder, James P.
Dirhodium(II) tetraacetate catalyzed decomposition of ethyl diazoacetate in the presence of D-Cbz-vinylglycine methyl ester (11) afforded a mixture of the cyclopropyl esters D-CGA A-D (13) from which the corresponding 2R-acids 7-10 were obtained and their absolute configurations assigned. The (2R,3S,4R) α-(carboxycyclopropyl)glycine (D-CGA C, 9 resulted to be the most potent and selective among the NMDA receptor ligands yet reported.
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