Nickel-catalysed Alkylative Alkenation of Orthothioesters with Grignard Reagents; a Convenient Procedure for introducing the Isopropenyl Group. Synthesis of Substituted 1,3-(Bis-trimethylsilyl)propenes

DOI: 10.1039/c39900000399

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 399 - 400 (1990)

Update date:2022-08-04

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Authors:

Tzeng, Yih-Ling

Luh, Tien-Yau

Fang, Jim-Min

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Article abstract of DOI:10.1039/c39900000399

Nickel-catalysed coupling of orthothioesters with MeMgI furnishes a general method for introducing the isopropenyl group; the application of this reaction to the synthesis of 1,3-(bis-trimethylsilyl)propenes is presented.

Full text of DOI:10.1039/c39900000399

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