Nickel-catalysed Alkylative Alkenation of Orthothioesters with Grignard Reagents; a Convenient Procedure for introducing the Isopropenyl Group. Synthesis of Substituted 1,3-(Bis-trimethylsilyl)propenes

DOI: 10.1039/c39900000399

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 399 - 400 (1990)

Update date:2022-08-04

Topics:

Authors:

Tzeng, Yih-Ling

Luh, Tien-Yau

Fang, Jim-Min

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900000399

Nickel-catalysed coupling of orthothioesters with MeMgI furnishes a general method for introducing the isopropenyl group; the application of this reaction to the synthesis of 1,3-(bis-trimethylsilyl)propenes is presented.

Full text of DOI:10.1039/c39900000399

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Silane, [2-(4-methylphenyl)-1-propene-1,3-diyl]bis[trimethyl-, (Z)-

Cas No:128155-70-4

R&D Labs maybe for 128155-70-4

Jintan Jinnuo Chemical Co., Ltd.

Contact:+86-519-80199901

Address:Room 1804, Building 1, Huacheng Business Plaza, Jintan, Jiangsu, China
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
SICHUAN ZHONGBANG NEW MATERIAL CO., LTD

website:http://www.zhongbangst.com

Contact:86-830-2585019

Address:sichuan,china
Suzhou Credit International Trading Co., Ltd

Contact:+86-512-65398039

Address:Qingdeng, Hightech. District, Suzhou
Tianjin Derchemist Sci-Tech Co., Ltd.

website:http://www.derchemist.com

Contact:+86-22-58627059

Address:Xinmao Science and Technology Park，Huayuan Industrial Park

Relevant to this article

Investigations into competitive cycloaddition/cyclization or elimination from 1,1-dimethyl-propargylcarbamates of anilines

Doi:10.1071/CH10344
(2011)
Synthesis of Inositol Phosphates

Doi:10.1021/ja00215a061
(1988)
On the role of anionic ligands in the site-selectivity of oxidative C-H functionalization reactions of arenes

Doi:10.1039/c3sc00017f
(2013)
Copper-catalysed synthesis of 3-hydroxyisoindolin-1-ones from benzylcyanide 2-iodobenzamides

Doi:10.1039/c9ob02329a
(2020)
Three-component synthesis of functionalized 1-Azabuta-1,3-dienes from alkyl isocyanides, activated acetylenes, and pyridin-2(1H)-one or isoquinolin-1(2H)-one

Doi:10.1080/00397911003611802
(2011)
Design, synthesis, and bioactivity of nortopsentin analogues containing 1,2,4-triazole moieties

Doi:10.1002/jhet.3817
(2019)

Article Doi