Nickel-catalysed Alkylative Alkenation of Orthothioesters with Grignard Reagents; a Convenient Procedure for introducing the Isopropenyl Group. Synthesis of Substituted 1,3-(Bis-trimethylsilyl)propenes

DOI: 10.1039/c39900000399

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 399 - 400 (1990)

Update date:2022-08-04

Topics:

Authors:

Tzeng, Yih-Ling

Luh, Tien-Yau

Fang, Jim-Min

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900000399

Nickel-catalysed coupling of orthothioesters with MeMgI furnishes a general method for introducing the isopropenyl group; the application of this reaction to the synthesis of 1,3-(bis-trimethylsilyl)propenes is presented.

Full text of DOI:10.1039/c39900000399

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Silane, [2-(4-methylphenyl)-1-propene-1,3-diyl]bis[trimethyl-, (Z)-

Cas No:128155-70-4

R&D Labs maybe for 128155-70-4

Shandong Yaroma Perfumery Co., Ltd.

Contact:+86- 531- 88024598

Address:7-702 Caizhi Central, 59 Gong Ye South Road, Jinan City,250101, P. R. China
Sinoway Industrial Co., Ltd.

website:http://www.china-sinoway.com

Contact:+86-592-5853819

Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China
sichuan tiancai fine co LTD.

website:http://www.tcfinechem.com/

Contact:18681346930

Address:baifu town,whou district
Shanghai Mio Chemical Co., Ltd

Contact:0086 21- 64401188-622

Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road

Relevant to this article

Investigations into competitive cycloaddition/cyclization or elimination from 1,1-dimethyl-propargylcarbamates of anilines

Doi:10.1071/CH10344
(2011)
Synthesis of Inositol Phosphates

Doi:10.1021/ja00215a061
(1988)
On the role of anionic ligands in the site-selectivity of oxidative C-H functionalization reactions of arenes

Doi:10.1039/c3sc00017f
(2013)
Copper-catalysed synthesis of 3-hydroxyisoindolin-1-ones from benzylcyanide 2-iodobenzamides

Doi:10.1039/c9ob02329a
(2020)
Three-component synthesis of functionalized 1-Azabuta-1,3-dienes from alkyl isocyanides, activated acetylenes, and pyridin-2(1H)-one or isoquinolin-1(2H)-one

Doi:10.1080/00397911003611802
(2011)
Design, synthesis, and bioactivity of nortopsentin analogues containing 1,2,4-triazole moieties

Doi:10.1002/jhet.3817
(2019)

Article Doi