Tetrahedron p. 793 - 802 (1990)
Update date:2022-07-31
Topics:
Sparfel, Daniel
Baranne-Lafont, Joele
Cuong, Nguyen Kim
Capdevielle, Patrice
Maumy, Michel
New oxygen-activating systems for dehydrogenation of 2-hydroxymethyl phenols 1 (a: R = tBu ; b: R = CH3; c : R = H) to the corresponding salicylaldehydes 3 are described. These systems are composed of a transition metal (M0 = Fe0 or Cu0), a transition metal ion (MnCln=Fe11Cl2 or Cu1Cl) in catalytic amount and molecular oxygen. The most active systems are Fe0FeCl2O2CH3OH and Cu0CuCl + FeCl2O2CH3OH. Based on all the results so far obtained a mechanistic hypothesis is proposed.
Contact:86-27-84888681
Address:Wuhan economic & technology development zone
Wuhan Konberd Biotech Co., Ltd.
Contact:+86-27-87205925
Address:NO.666, Gaoxin Road, Eastlake High-tech zone
Geen Chemical Technology Co., Ltd
Contact:86-769-21660847
Address:1408, Yingfeng Commercial Center, Nancheng District
Jewim Pharmaceutical (Shandong) Co., Ltd
Contact:+8615621883869
Address:山东省泰安市高新技术产业开发区配天门大街西首
Contact:+91 - 22 - 26355700
Address:17, Lotus Business Park, Andheri West
Doi:10.1016/j.tet.2011.01.019
(2011)Doi:10.1021/jo200339w
(2011)Doi:10.1021/jo501433c
(2014)Doi:10.1016/S0040-4039(01)93337-4
(1989)Doi:10.1021/jo00302a021
(1990)Doi:10.1016/0040-4039(90)87030-4
(1990)
