Tetrahedron p. 793 - 802 (1990)
Update date:2022-07-31
Topics:
Sparfel, Daniel
Baranne-Lafont, Joele
Cuong, Nguyen Kim
Capdevielle, Patrice
Maumy, Michel
New oxygen-activating systems for dehydrogenation of 2-hydroxymethyl phenols 1 (a: R = tBu ; b: R = CH3; c : R = H) to the corresponding salicylaldehydes 3 are described. These systems are composed of a transition metal (M0 = Fe0 or Cu0), a transition metal ion (MnCln=Fe11Cl2 or Cu1Cl) in catalytic amount and molecular oxygen. The most active systems are Fe0FeCl2O2CH3OH and Cu0CuCl + FeCl2O2CH3OH. Based on all the results so far obtained a mechanistic hypothesis is proposed.
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
MOKESI TECHNOLOGY CO., LIMITED
Contact:000000000000
Address:NO.168 ,Weisi Road, Zhengzhou City,Henan,China
Chengda Pharmaceuticals Co., Ltd.
Contact:+86-573-84601188
Address:hengshan Road 5# in Jiashan, zhejiang
Shanghai PengMo Biotechnology Co.,Ltd
website:http://www.pengmobio.lookchem.com
Contact:86-13052359378
Address:No.218 Hai Qu Road.Shanghai.China
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Doi:10.1016/j.tet.2011.01.019
(2011)Doi:10.1021/jo200339w
(2011)Doi:10.1021/jo501433c
(2014)Doi:10.1016/S0040-4039(01)93337-4
(1989)Doi:10.1021/jo00302a021
(1990)Doi:10.1016/0040-4039(90)87030-4
(1990)
