Tetrahedron Letters p. 3345 - 3348 (1998)
Update date:2022-08-05
Topics:
Allin, Steven M.
Button, Martin A. C.
The anionic amino-Cope rearrangement of suitably functionalized acyclic 3-amino-1,5-diene substrates has been achieved and we report the first example of an asymmetric anionic amino-Cope rearrangement to yield an enantiomerically enriched product (75% e.e.). The absolute stereochemistry of the products has been verified and transition state models are proposed to rationalize the stereochemical outcome.
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