KONJUGIERTE ADDITION VON ALKYLDERIVATEN DER SPAETEN UEBERGANGSMETALLE Ag, Pd, Rh, Ru, Co UND Fe AN 2-CYCLOHEXENON

DOI: 10.1016/0040-4039(90)80014-D

Source and publish data:

Tetrahedron Letters p. 1553 - 1556 (1990)

Update date:2022-08-05

Topics:

Authors:

Kauffmann, Thomas

Huelsduenker, Achim

Menges, Detlef

Nienaber, Hubert

Rethmeier, Lutz

et al. et al.

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Article abstract of DOI:10.1016/0040-4039(90)80014-D

In situ prepared alkyl derivatives of the 4d metals Ag, Rh (Alk = Me, n-Bu), Pd, Ru (Alk = Me) alkylate 2-cyclohexenone (1) exclusively or preferently in β-position to the keto group.The same was observed by applying Me2Fe, Me3FeLi or the hetero-ate complexes Me2(t-BuO)2FeLi2 and Me2(t-BuO)2CoLi2, whereas Me4FeLi2 methylates 1 at the keto group.

Full text of DOI:10.1016/0040-4039(90)80014-D

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