Tetrahedron Letters p. 1553 - 1556 (1990)
Update date:2022-08-05
Topics:
Kauffmann, Thomas
Huelsduenker, Achim
Menges, Detlef
Nienaber, Hubert
Rethmeier, Lutz
et al.
In situ prepared alkyl derivatives of the 4d metals Ag, Rh (Alk = Me, n-Bu), Pd, Ru (Alk = Me) alkylate 2-cyclohexenone (1) exclusively or preferently in β-position to the keto group.The same was observed by applying Me2Fe, Me3FeLi or the hetero-ate complexes Me2(t-BuO)2FeLi2 and Me2(t-BuO)2CoLi2, whereas Me4FeLi2 methylates 1 at the keto group.
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(1990)
