SYNTHESIS OF VINYLCYCLOPROPANES VIA PALLADIUM-CATALYZED COUPLING OF CYCLOPROPYLZINC HALIDES WITH VINYL IODIDES. TOTAL SYNTHESES OF (+/-)-PREZIZANOL AND (+/-)-PREZIZAENE

DOI: 10.1016/S0040-4039(00)95593-X

Source and publish data:

Tetrahedron Letters p. 5075 - 5078 (1987)

Update date:2022-07-29

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Authors:

Piers, Edward

Jean, Michel

Marrs, Peter S.

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Article abstract of DOI:10.1016/S0040-4039(00)95593-X

Palladium(0)-catalyzed coupling of cyclopropylzinc halides, readily prepared from the corresponding cyclopropyl(tri-n-butyl)stannanes, with vinyl iodides provides good yields of functionalized vinylcyclopropanes.The coupling reaction is used as a key step in total syntheses of the sesquiterpenoids (+/-)-prezizanol and (+/-)-prezizaene.

Full text of DOI:10.1016/S0040-4039(00)95593-X

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