Tetrahedron Letters p. 5075 - 5078 (1987)
Update date:2022-07-29
Topics:
Piers, Edward
Jean, Michel
Marrs, Peter S.
Palladium(0)-catalyzed coupling of cyclopropylzinc halides, readily prepared from the corresponding cyclopropyl(tri-n-butyl)stannanes, with vinyl iodides provides good yields of functionalized vinylcyclopropanes.The coupling reaction is used as a key step in total syntheses of the sesquiterpenoids (+/-)-prezizanol and (+/-)-prezizaene.
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