Reactions of the trigonal-bipyramidal cobalt(I) hydride [{P(CH2CH2PPh2)3}CoH] with 1-alkynes. Synthesis and reactivity of acetylide, alkenyl, and vinylidene complexes

DOI: 10.1021/om00159a021

Source and publish data:

Organometallics p. 2514 - 2522 (1990)

Update date:2022-08-04

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Authors:

Bianchini, Claudio

Innocenti, Paolo

Meli, Andrea

Peruzzini, Maurizio

Zanobini, Fabrizio

Zanello, Piero

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Article abstract of DOI:10.1021/om00159a021

The reactions of HC≡CR (R = CO₂Et, Ph, n-C₅H₁₁) with the Co(I) hydride [(PP₃)CoH] (1) are influenced by a number of factors, including stoichiometry, alkyne substituent, and temperature (PP₃ = P-(CH View More

Full text of DOI:10.1021/om00159a021

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Product name:{P(CH₂CH₂P(C₆H₅)2)3}CoH⁽¹⁺⁾*PF₆^(1-)={CoHP(CH₂CH₂P(C₆H₅)2)3}PF₆

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