Synthetic and Kinetic Studies of the Intramolecular Diels-Alder Reactions of Cycloalkenylallenylphosphine Oxides

DOI: 10.1021/jo00305a025

Source and publish data:

Journal of Organic Chemistry p. 5278 - 5287 (1990)

Update date:2022-07-29

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Authors:

Curtin, Michael L.

Okamura, William H.

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Article abstract of DOI:10.1021/jo00305a025

Kinetic investigations reveal that diphenylphosphinoyl (diphenylphosphine oxide) substituted cycloalkenylallenes 13b-d undergo intramolecular Diels-Alder (IMDA) cyclizations at room temperature to afford adducts with gem-dialkyl effect accelerations of 4.

Full text of DOI:10.1021/jo00305a025

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