Synthetic and Kinetic Studies of the Intramolecular Diels-Alder Reactions of Cycloalkenylallenylphosphine Oxides

DOI: 10.1021/jo00305a025

Source and publish data:

Journal of Organic Chemistry p. 5278 - 5287 (1990)

Update date:2022-07-29

Topics:

Authors:

Curtin, Michael L.

Okamura, William H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00305a025

Kinetic investigations reveal that diphenylphosphinoyl (diphenylphosphine oxide) substituted cycloalkenylallenes 13b-d undergo intramolecular Diels-Alder (IMDA) cyclizations at room temperature to afford adducts with gem-dialkyl effect accelerations of 4.

Full text of DOI:10.1021/jo00305a025

Products guided by the article

Product name:(8R*,10S*)-2-(diphenylphosphinoyl)tricyclo<8.3.0.0^3,8>trideca-1,3-diene

Cas No:129031-93-2

R&D Labs maybe for 129031-93-2

Hangzhou LINGEBA Technology Co., Ltd.

Contact:+0086-571-87389059

Address:Office 1-913,NewYouth Plaza, GongShu Area, HangZhou,ZheJiang,P.R.China
JADECHEM NINGBO CO.,LTD.

Contact:+86-574-89075960

Address:#100 Xiang Yun Road, New High tech area, Ningbo, China
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
ANHUI WEICHI CHEMICAL CO.,LTD

website:http://www.weichichem.com

Contact:+8613912949432

Address:Fine Chemical Industrial Base,Wujiang town,He County,Anhui China.
Winchem Industrial Co. Ltd.(expird)

Contact:86-574-83851061 86-574-87083208

Address:Room 905, No.3 Building,East Business Center, 456 Xingning Road, Ningbo City,China

Relevant to this article

A NEW SYNTHESIS, RESOLUTION AND IN VITRO ACTIVITIES OF (R)- AND (S)-β-PHENYL-GABA

Doi:10.1016/S0040-4020(01)82032-9
(1990)
DNA cleavage and antitumor activity of designed molecules with conjugated phosphine oxide-allene-ene-yne functionalities

Doi:10.1021/ja00177a070
(1990)
FLUOROOLEFIN DIPEPTIDE ISOSTERES - I. The Synthesis of GlyΨ(CF=CH)Gly and Racemic PheΨ(CF=CH)Gly

Doi:10.1016/S0040-4039(00)88548-2
(1990)
A safe and practical procedure for the difluoromethylation of methyl 4-hydroxy-3-iodobenzoate

Doi:10.1021/op200052z
(2011)
Identification of novel metabolic pathways of pioglitazone in hepatocytes: N-glucuronidation of thiazolidinedione ring and sequential ring-opening pathway

Doi:10.1124/dmd.109.031583
(2010)
Synthesis of polyfunctional allenes by successive copper-mediated substitutions

Doi:10.1002/chem.201003273
(2011)

Article Doi