Tetrahedron Letters p. 1451 - 1454 (1990)
Update date:2022-08-03
Topics:
Harger
The hydroxylamine derivative Ph2P(O)NHOP(O)Ph2 rearranges on treatment with Bu(t)OK-Bu(t)OH; the product contains two dissimilar P atoms (δ(p) 24.2 and 7.9, J(pp) 34 Hz) and is rapidly hydrolysed to a phosphonamidate and a phosphinate, consistent with it being the mixed anhydride Ph(PhNH)P(O)OP(O)Ph2.
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(1990)Doi:10.1021/ol2012154
(2011)Doi:10.1016/j.bmcl.2011.04.104
(2011)
