An Efficient Route to Chiral trans-2,5-Dialkylpyrrolidines via Stereoselective Intramolecular Amidomercuration

DOI: 10.1016/S0957-4166(00)80547-9

Source and publish data:

Tetrahedron Asymmetry p. 561 - 566 (1990)

Update date:2022-08-03

Topics:

Authors:

Takahata, Hiroki

Takehara, Hiroyuki

Ohkubo, Naoki

Momose, Takefumi

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Article abstract of DOI:10.1016/S0957-4166(00)80547-9

An intramolecular amidomercuration of α-butylated 4-pentenylcarbamate 5 predominantly provided trans-2,5-disubstituted pyrrolidine 6, which was elaborated to chiral trans-5-butyl-2-alkylpyrrolidines 10 and 13, constituents of ant venoms.

Full text of DOI:10.1016/S0957-4166(00)80547-9

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Product name:(2S,5R)-1-benzyloxycarbonyl-2-butyl-5-(1-heptenyl)pyrrolidine

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