Journal of Fluorine Chemistry p. 527 - 532 (1990)
Update date:2022-08-02
Topics:
Banks, R. Eric
Madany, Ismail M.
Thermolysis of perfluoro-4-azidopyridine and perfluoro-4-azidotoluene in the presence of a large excess (10 molar) of pentamethylbenzene gave mainly (>60percent) products expected from nitrene 'insertions' at the nuclear C-H bond, i.e.ArFNHC6Me5 (ArF = 4-C5F4N, 4-C6F4CF3).Similar decomposition of perfluoro-4-azidotoluene in hexamethylbenzene gave a complex mixture containing perfluoro-p-toluidine.
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