Efficient asymmetric hydrogenation of (Z)-2-acetamidocinnamic acid catalyzed by the rhodium complex of modified n-Benzyl-(3R,4R)-3,4-bis(diphenylphosphino)pyrrolidine (degphos)

Article abstract of DOI:10.1248/cpb.38.818

Modified Degphoses (R,R)-MOD-, XYL-Degphos) have been prepared and catalytic asymmetric hydrogenetion of (Z)-2-acetamidocinnamic acid was carried out with their rhodium(]) cationic complexes. The catalytic activities of the modified Degphoses were enhanced.

Full text of DOI:10.1248/cpb.38.818

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