Synthese und Reaktivitaet von Phenylethinyl-substituierten Phosphenium-Ion-Komplexen (R)(R')P=MoCp'(CO)2; Darstellung von Clusterverbindungen, die einen 1-Cobalta-2-Phospha-Heteroallyl Synthesebaustein enthalten

DOI: 10.1016/0022-328X(90)80007-M

Source and publish data:

Journal of Organometallic Chemistry p. 349 - 363 (1990)

Update date:2022-09-26

Topics: Darstellung

Authors:

Lang, Heinrich

Leise, Michael

Zsolnai, Laszlo

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Article abstract of DOI:10.1016/0022-328X(90)80007-M

The synthesis of the phenylethinyl-chlorophosphines (R)(Cl)P(C<*>C-Ph) (R = 2,6-^tBu2-4-MeC6H2O: IVa; R = 2,4,6-^tBu3C6H2O: IVb) is described.IV reacts with Cp'(CO)3Mo^-, VII, (Cp' = η⁵-C5H5, ν⁵-C5Me5) t

Full text of DOI:10.1016/0022-328X(90)80007-M

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Product name:(2,4,6-t-Bu₃C₆H₂O)phenylethinyl-chlorophosphine

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