Synthesis p. 453 - 454 (1990)
Update date:2022-09-26
Topics:
Saari, Walfred S.
Fisher, Thorsten E.
Preparation of optically pure aliphatic and allylic amines from amino acids is described.Wittig olefination of α-Boc-amino aldehydes affords Boc-prodected allylic amines which can be deprotected to the corresponding chiral unsaturated amines.Catalytic reduction of the Wittig product prior to deprotection affords aliphatic amines of high optical purity.
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Doi:10.1002/cmdc.201000507
(2011)Doi:10.1021/jo200031u
(2011)Doi:10.1016/0008-6215(90)84202-6
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(2013)Doi:10.1016/j.poly.2012.02.035
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(2011)
