Synthesis p. 453 - 454 (1990)
Update date:2022-09-26
Topics:
Saari, Walfred S.
Fisher, Thorsten E.
Preparation of optically pure aliphatic and allylic amines from amino acids is described.Wittig olefination of α-Boc-amino aldehydes affords Boc-prodected allylic amines which can be deprotected to the corresponding chiral unsaturated amines.Catalytic reduction of the Wittig product prior to deprotection affords aliphatic amines of high optical purity.
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Doi:10.1002/cmdc.201000507
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(1990)Doi:10.1039/c2ob26762d
(2013)Doi:10.1016/j.poly.2012.02.035
(2012)Doi:10.1002/ejoc.201001739
(2011)
