
Australian Journal of Chemistry p. 719 - 732 (1990)
Update date:2022-07-29
Topics:
Hayman, Alan R.
Hanton, Lyall R.
Weavers, Rex T.
2-Azalauren-1-ene (2) has been synthesized from keto acid (5), but attempts to generate its C 15 epimer (19) have produced only (2).Model studies of imine production by treatment of a rimuene-derived keto acid (3) with iodosylbenzene/formic acid have produced a hydroxyimine (11), a conjugated imine (13), and a keto lactam (12) which has a ten-membered ring.An X-ray crystallographic study which proves the structure of (12) is described.Data in support of the intermediacy of imine (7) (6-azadihydrorimuene) in the production of (11), (12) and (13) have been obtained.
View MoreShanghai better-in Medical Technology Co.,LTD.
Contact:+86-21-38921049
Address:Lane 720 zhangjianggaoke cailun road, Pudong, Shanghai, room 513
Contact:+36(21)2523420
Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Shanghai PuYi Chem-Tech Co.,Ltd.
Contact:+86-21-57687505-227
Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China
Contact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Yingkou Sanzheng New Technology Chemical Industry Co., Ltd.
Contact:+86-417-2927806
Address:yingkou
Doi:10.1080/00397911003797874
(2011)Doi:10.1002/ejoc.201001611
(2011)Doi:10.1016/S0040-4039(03)00897-9
(2003)Doi:10.1016/S0040-4039(00)98790-2
(1990)Doi:10.1016/j.bioorg.2019.01.017
(2019)Doi:10.1021/jo502577e
(2015)