Photooxygenation of 3- and 2-silyloxybenzofurans: Rearrangement of dioxetanes via α-silylperoxy ketones to ketoester cleavage products

DOI: 10.1016/0040-4039(90)80200-6

Source and publish data:

Tetrahedron Letters p. 2259 - 2262 (1990)

Update date:2022-08-04

Topics:

Authors:

Adam Adam

Kades Kades

Wang Wang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(90)80200-6

Photooxygenation of 2-methyl-3-silyloxybenzofurans 1 afforded isolable dioxetranes 2, the latter rearranged via α-silylperoxy ketones 3 to cleavage products 4; 2-silyloxy-3-methylbenzofuran 6 with ¹O₂ gave the more stable dioxetane 7.

Full text of DOI:10.1016/0040-4039(90)80200-6

Products guided by the article

Product name:C₁₅H₂₂O₄Si

Cas No:129512-47-6

R&D Labs maybe for 129512-47-6

ZHEJIANG CHEMICAL INDUSTRY INSTITUTE TECHNOLOGY CO.,LTD(expird)

Contact:86-575-82730298

Address:shangyu
Hangzhou Haichem Co.,Ltd.

Contact:+86-571-86025531 / 86024803

Address:1218-24 Guangyin Mansion,42 Fengqi East Road
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street
Nanjing Spring & Autumn Biological Engineering Co., Ltd.

Contact:86-180510-83338

Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
Nantong Chem-land Co., Ltd.

Contact:86 513 85512619

Address:Rm.1306, Building A, Wenfeng Mansion,168 Gongnong Road, Nantong Jiangsu China

Relevant to this article

STRUCTURE-ACTIVITY RELATIONSHIP OF NSTX-3, SPIDER TOXIN OF NEPHILA MACULATA

Doi:10.1016/S0040-4020(01)90516-2
(1990)
Regio- and Stereochemistry in Electrophilic Reactions of 2-Propenyl-1,3-dithiane 1-Oxide

Doi:10.1021/jo00307a025
(1990)
The development of a novel series of (quinolin-2-ylmethoxy)phenyl-containing compounds as high-affinity leukotriene receptor antagonists. 3. Structural variation of the acidic side chain to give antagonists of enhanced potency

Doi:10.1021/jm00172a024
(1990)
Highly regio- and stereoselective synthesis of tetracyclic indolenoisoxazolidines via intramolecular 1,3-dipolar nitrone cycloadditions

Doi:10.1055/s-0032-1317928
(2013)
Formation and reactivity of gem-difluoro-substituted pyridinium ylides: Experimental and DFT investigation

Doi:10.1016/j.jfluchem.2010.12.013
(2011)
A photoreactive probe that differentiates the binding sites of noncompetitive GABA receptor antagonists

Doi:10.1016/j.bmcl.2011.01.118
(2011)

Article Doi