Regio- and Stereochemistry in Electrophilic Reactions of 2-Propenyl-1,3-dithiane 1-Oxide

DOI: 10.1021/jo00307a025

Source and publish data:

Journal of Organic Chemistry p. 5515 - 5519 (1990)

Update date:2022-08-04

Topics:

Authors:

Fang, Jim-Min

Chou, Wen-Chih

Lee, Gene-Hsiang

Peng, Shie-Ming

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Article abstract of DOI:10.1021/jo00307a025

The unsymmetrical allyllithium generated from 2-propenyl-1,3-dithiane 1-oxide (2) reacted at the α-site with halides and most of the carbonyl compounds tried.The α-addition reactions occurred predominantly on the face syn to the sulfinyl group.The α-syn a

Full text of DOI:10.1021/jo00307a025

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