Tetrahedron Letters p. 3749 - 3752 (1990)
Update date:2022-08-05
Topics:
Sakakibara, Tohru
Takaib, Izumi
Yamamotok, Azuma
Iizuka, Hiroyuki
Hirasawa, Kohji
Ishido, Yoshiharu
Reactions of the title compounds with sodium methoxide and sodium borodeuteride were found to proceed mainly via the SN2′ mechanism; nucleophiles selectively attacked the anomeric carbon atom from the same side of the leaving acetoxyl group at C-3.
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