Journal of Organometallic Chemistry p. 61 - 68 (1993)
Update date:2022-08-03
Topics:
Hitchcock, Peter B.
Matos, Robson M.
Meidine, Mohamed F.
Nixon, John F.
Passos, Bernadette F. Trigo
et al.
The synthesis and characterisation of Pt0, PtII, PdII, RhI, and W0 complexes containing the RP(NR')P=CR'(R=Et3C, R'=t-Bu) ring system are reported, and their NMR spectroscopic data are discussed.Low oxidation state metal fragments bond through the two-coordinate phosphorus, whereas the three-coordinate phosphorus atom is the donor towards PdII and PtII.Both phosphorus atoms are ligated in a dinuclear PtII complex.
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