Syntheses and NMR spectroscopic characterisation of transition metal complexes containing the azadiphosphetine ring system RP(NR')P=CR' (R=Et3C, R'=tBu)

DOI: 10.1016/0022-328X(93)83274-Y

Source and publish data:

Journal of Organometallic Chemistry p. 61 - 68 (1993)

Update date:2022-08-03

Topics:

Authors:

Hitchcock, Peter B.

Matos, Robson M.

Meidine, Mohamed F.

Nixon, John F.

Passos, Bernadette F. Trigo

et al. et al.

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Article abstract of DOI:10.1016/0022-328X(93)83274-Y

The synthesis and characterisation of Pt⁰, Pt^II, Pd^II, Rh^I, and W⁰ complexes containing the RP(NR')P=CR'(R=Et3C, R'=t-Bu) ring system are reported, and their NMR spectroscopic data are discussed.Low oxidation state metal fragments bond through the two-coordinate phosphorus, whereas the three-coordinate phosphorus atom is the donor towards Pd^II and Pt^II.Both phosphorus atoms are ligated in a dinuclear Pt^II complex.

Full text of DOI:10.1016/0022-328X(93)83274-Y

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