Asymetric Electrophilic α-Amidoalkylation, VII: Generation, Crystal Structure, and Trapping Reactions of a Chiral 6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoline Derived N-Acyliminium Ion

DOI: 10.1002/ardp.19903230605

Source and publish data:

Archiv der Pharmazie p. 335 - 350 (1990)

Update date:2022-08-05

Topics:

Authors:

Wanner, Klaus Th.

Praschak, Ilona

Nagel, Ulrich

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Article abstract of DOI:10.1002/ardp.19903230605

The camphanic acid amide 4 has efficiently been oxidized with triphenylcarbenium tetrafluoroborate (3) to yield the chiral N-acyliminium ion 1.Trapping reactions of 1 with the silyl nucleophiles 7a-c and 10a-f proceeded with stereoselective bond formation

Full text of DOI:10.1002/ardp.19903230605

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