Organic and Biomolecular Chemistry p. 2743 - 2750 (2011)
Update date:2022-08-04
Topics:
Bukovec, Christian
Kazmaier, Uli
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl]2 as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized buiding blocks in excellent yields.
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