Unexpected Acid-catalysed Rearrangement of Certain 3-(Arylthio)indoles to 2-(2-Aminophenyl)benzothiophenes

DOI: 10.1039/c39900001072

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1072 - 1074 (1990)

Update date:2022-08-06

Topics:

Authors:

Hamel, Pierre

Girard, Yves

Atkinson, Joseph G.

Bernstein, Michael A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001072

3-(Arylthio)indoles (1), in which the aryl group is an electron-rich ring system, undergo a novel structural rearrangement to 2-(2-aminophenyl)benzothiophenes (2) upon heating in polyphosphoric acid.

Full text of DOI:10.1039/c39900001072

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1H-Indole, 2-[(3-methoxyphenyl)thio]-

Cas No:130128-93-7

R&D Labs maybe for 130128-93-7

Guangzhou Reachin Chemical Co., Ltd

Contact:+86-20-37087379 ext.604

Address:A122C-1, Tianyuan Plaza, 401 Tianyuan Rd., Tianhe, Guangzhou, China
Shenzhen HwaGen Pharmaceutical Co., Ltd

website:http://www.rafflespt.com

Contact:+86-752-5538396

Address:Guangdong Huizhou China
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
ShangHai Soyoung Biotechnology Inc

website:http://www.soyoungbio.com

Contact:+86-21-69893009

Address:shanghai
zhangjiagang bonded areas banggao co;ltd

website:http://www.shunchangchem.com

Contact:0086-13921972933

Address:Dongsha Chemical Zone.Zhangjiagang, Jiangsu Province

Relevant to this article

Transition-Metal-Free Selective Oxidative C(sp³)-S/Se Coupling of Oxindoles, Tetralone, and Arylacetamides: Synthesis of Unsymmetrical Organochalcogenides

Doi:10.1021/acs.orglett.6b03735
(2017)
Synthesis of sulfonamide-containing N-hydroxyindole-2-carboxylates as inhibitors of human lactate dehydrogenase-isoform 5

Doi:10.1016/j.bmcl.2011.10.031
(2011)
Asymmetric intramolecular aldol reaction mediated by (S)-N-substituted-N- (2-pyrrolidinylmethyl)amine to prepare Wieland-Miescher ketone

Doi:10.3987/COM-10-S(E)119
(2011)
Hexamethyldisilazane-promoted sonogashira reaction of polyfunctionalized N-containing heterocycles

Doi:10.3987/COM-10-S(E)89
(2011)
Highly enantioselective synthesis of fluorinated β-amino ketones via asymmetric organocatalytic Mannich reactions: A case study of unusual reversal of regioselectivity

Doi:10.1055/s-0030-1259513
(2011)
POLYFLUORO-1,2-EPOXY- ALKANES AND -CYCLOALKANES. PART VI. THE SYNTHESIS AND SOME REACTIONS OF 1-TRIFLUOROMETHYLNONAFLUORO-1,2-EPOXYCYCLOHEXANE

Doi:10.1016/S0022-1139(00)80360-7
(1990)

Article Doi