Tetrahedron p. 11501 - 11516 (1998)
Update date:2022-08-05
Topics: Workup and Purification Stereochemistry Control Staudinger Reaction Formation of Chiral Imines
Barreau, Michel
Commercon, Alain
Mignani, Serge
Mouysset, Dominique
Perfetti, Patricia
Stella, Lucien
Selected imines of methyl glyoxylate act as good partners in the Staudinger cycloaddition reaction with a series of substituted ketenes. The cis stereoselectivity is almost complete with electron-donor substituted ketenes, but the asymmetric induction is low when imines derived from chiral l-aryl-ethylamines are used.
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