Tetrahedron Letters p. 3069 - 3072 (1994)
Update date:2022-08-02
Topics:
Cahiez, Gerard
Chau, Khi
Clery, Patrick
Li-enolates are readily converted to Mn-enolates by treatment with manganese halides.In THF, the reaction is easily and economically performed with manganese chloride at room temperature.Mn-enolates can then be regioselectively monoalkylated in good yields.The formation of di and polyalkylated products is never observed (<1percent).
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