Boron Mediated One-Pot Aldol-reduction Sequence: Enantio and Diastereoselective Synthesis of Typical Polyketide Fragments

DOI: 10.1016/S0957-4166(00)86165-0

Source and publish data:

Tetrahedron Asymmetry p. 173 - 176 (1994)

Update date:2022-08-02

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Authors:

Bonini, Carlo

Racioppi, Rocco

Righi, Giuliana

Rossi, Leucio

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Article abstract of DOI:10.1016/S0957-4166(00)86165-0

An aldol-reduction one-pot sequence allows syn-syn polyketide fragments such as 7 to be obtained enantio and diastereoselectively.Enol diisopinocampheylborinate is able to influence both the aldol and the subsequent reduction with NaBH4 via a chelate chair like intermediate.

Full text of DOI:10.1016/S0957-4166(00)86165-0

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