Tetrahedron Letters p. 2669 - 2672 (1990)
Update date:2022-08-03
Topics: Synthesis Synthetic studies Nucleophile Electrophile Rearrangement Reagent Fragment Epoxide Carboxylic acid Isomer Base DNA Intercalation Ring Strain Cyclic ether antitumor antibiotic Oxirane Carzinophilin
England, Pamela
Chun, Keun Ho
Moran, Edmund J.
Armstrong, Robert W.
An efficient synthesis of the epoxide-containing fragment 4 of carzinophilin has been completed. Intramolecular acyl transfer of a related epoxide afforded amide 16. Comparison by 1H NMR of 4 and 16 with authentic natural product provides further evidence for structural revision of carzinophilin.
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Doi:10.1002/adsc.201201017
(2013)Doi:10.1016/j.cclet.2021.02.052
(2021)Doi:10.1021/ja00207a038
(1989)Doi:10.1021/ja00179a010
(1990)Doi:10.1016/j.bmcl.2011.02.016
(2011)Doi:10.1016/S0040-4039(00)94734-8
(1990)
